The trans–perp conformer of peroxynitrous acid is identified by action spectroscopy in the OH overtone region and assigned by simulating its band structure using a transition moment and rotational constants from ab initio theory. The highest observed OH product state sets an upper limit for the O–O bond energy of tp-HOONO of 16.8 kcal/mol.
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Pollack et al. (2003) studied this question.
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