Organocatalytic One‐Pot Asymmetric Synthesis of Functionalized Tricyclic Carbon Frameworks from a Triple‐Cascade/Diels–Alder Sequence

Hitting the teens! Five CC bonds and eight stereocenters were formed in a one-pot asymmetric multicomponent domino reaction, which led to the functionalized tricyclic diterpenoid-type core structures (see scheme, IMDA=intramolecular Diels–Alder reaction). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z603434_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.