Controlled synthesis processes of cobalt containing borates in a multi-component flux system based on Bi ₂ O ₃ –MoO ₃ –Na ₂ O–B ₂ O ₃

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Targeted Ni2+ doping in cobalt-containing borates shifts the Co3−xNixB2O6–Co3−xNixBO5 phase boundary, enabling reversible switching at the triple point (x=1) and allowing for precise synthesis control and redox management. Novelty: ClaimNovelty.INCREMENTAL. Consensus alignment: ConsensusAlignment.NEUTRAL.

Evgeniya Moshkina; Maxim S. Molokeev; Svetlana Sofronova; E. V. Eremin; Dieter Kokh; Ruslan Germanovich Batulin; М.А. Черосов; A. V. Shabanov; Leonard Bezmaternykh

doi:10.1039/d5tc03374h

January 1, 2026Journal of Materials Chemistry C

Controlled synthesis processes of cobalt containing borates in a multi-component flux system based on Bi ₂ O ₃ –MoO ₃ –Na ₂ O–B ₂ O ₃

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Abstract

Targeted Ni 2+ doping shifts the Co 3− x Ni x B 2 O 6 –Co 3− x Ni x BO 5 phase boundary and enables reversible switching at Co 3 B 2 O 6 –Co 3− x Ni x BO 5 –Ni 3 B 2 O 6 triple point at x = 1. The precise synthesis control and redox management in cobalt materials are demonstrated.

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Moshkina et al. (2026) studied this question.

synapsesocial.com/papers/6a214c83589de9df3302ed7d https://doi.org/10.1039/d5tc03374h

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Controlled synthesis processes of cobalt containing borates in a multi-component flux system based on Bi ₂ O ₃ –MoO ₃ –Na ₂ O–B ₂ O ₃

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Controlled synthesis processes of cobalt containing borates in a multi-component flux system based on Bi ₂ O ₃ –MoO ₃ –Na ₂ O–B ₂ O ₃

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