A marked concentration dependence was observed for the circular dichroism of poly-γ-(1-naphthylmethyl)-l-glutamate in ethylene chlorohydrin. This fact was explained in terms of the formation of the β-structure in the solution at high concentrations of the polyglutamate and the subsequent restriction of the side chain orientation relative to the dissymmetric field in the solution.
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Enomoto et al. (1974) studied this question.
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