Temperature Below 30 mK Achieved by Adiabatic Demagnetization Refrigeration

Adiabatic demagnetization refrigeration (ADR) is the only technique capable of reaching ultralow temperatures without helium-3 and plays a crucial role at the forefront of both fundamental and applied science. However, progress in ADR is constrained by the limited magnetic entropy change (−ΔSm) of existing refrigerants at ultralow temperatures. This limitation primarily stems from the inherent contradiction of simultaneously attaining a large −ΔSm and a low magnetic ordering temperature (T0) in magnetic refrigerant design. Here, we show that a magnetic refrigerant exhibiting both a large −ΔSm and a low T0 can be simultaneously achieved by incorporating weak magnetic exchange and dipolar interactions into the dense frustrated magnet KYb3F10 (1). Notably, the average −ΔSm of 1 in the 0.05–1.0 K range surpasses those of commercial refrigerants (NH4)Fe(SO4)2·12H2O and CrK(SO4)2·12H2O by 146 and 219%, respectively, while its T0 is lower than 50 mK. Practical ADR testing confirms that a minimum temperature of 27.2 mK can be reached under a magnetic field of 6 T using 1 as the refrigerant. Thus, this work not only presents a high-performance ultralow-temperature refrigerant but also addresses the long-standing challenge of simultaneously achieving a large −ΔSm and a low T0 in the design of magnetic refrigerants.