Through‐Space Electronic Energy Transfer Across Proximal Molecular Dyads

Energy transfer: For large electronic systems in close proximity it is shown that the coulombic mechanism accounts for the rates of electronic energy transfer for both linear and perpendicular geometries across distances from 36 to 16 Å. Replacing the ideal dipole approximation with either a revised extended dipole or atom-localized charges improves agreement between theory and experiment. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.