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March 18, 2008Journal of the American Chemical Society590 citations

Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of γ-SiW10O368−: A Totally Inorganic Oxygen-Evolving Catalyst

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ASAndrea SartorelMCMauro CarraroGSGianfranco Scorrano

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Abstract

Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h-1.

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Cite This Study

Sartorel et al. (2008) studied this question.

synapsesocial.com/papers/6a22b4d329c8bdba62cd5f92https://doi.org/10.1021/ja077837f
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