Controlling Localized Plasmons via an Atomistic Approach: Attainment of Site-Selective Activation inside a Single Molecule

Chemical reactions such as bond dissociation and formation assisted by localized surface plasmons (LSPs) of noble metal nanostructures hold promise in solar-to-chemical energy conversion. However, the precise control of localized plasmons to activate a specific moiety of a molecule, in the presence of multiple chemically equivalent parts within a single molecule, is scarce due to the relatively large lateral distribution of the plasmonic field. Herein, we report the plasmon-assisted dissociation of a specific molecular site (C-Si bond) within a polyfunctional molecule adsorbed on a Cu(100) surface in the scanning tunneling microscope (STM) junction. The molecular site to be activated can be selected by carefully positioning the tip and bringing the tip extremely close to the molecule (atomistic approach), thereby achieving plasmonic nanoconfinement at the tip apex. Furthermore, multiple reactive sites are activated in a sequential manner at the sub-molecular scale, and different sets of products are created and visualized by STM topography and density functional theory (DFT) modeling. The illustration of site-selective activation achieved by localized surface plasmons implies the realization of molecular-scale resolution for bond-selected plasmon-induced chemistry.