No flame, no gain: A hypergolic mixture is composed of stable species that readily react/ignite on molecular contact. Both the anion and the cation in an ionic liquid play prominent roles in determining hypergolic properties as well as ignition delay times. With the 2,2-dialkyltriazanium cation, salts with nitrate, chloride, nitrocyanamide, and dicyanamide anions are hypergolic.
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Gao et al. (2009) studied this question.
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