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Application of the dimensional method of vector lengths to the continuity equations for momentum, heat, and any conservative scalar property whose mass concentration is S , yields a flux‐gradient relationship of the form {article}{empty}{document}\[ Kz r_ω Sσ S∂ S ∂ z = fS \ KgzH ρ cₚ Tσ ω ³ \ \]{document} Which is identical to the Monin‐Obukhov relationship except that the governing parameter u * is replaced by σ ω and the governing parameter S * is replaced by γ ω S σ S . This formulation cannot be adequately tested with existing data due to a systematic underestimation of the rapid‐response statistics under non‐neutral conditions. This underestimation is the result of improper choice of sampling period and interval between successive measurements. While a satisfactory correction may be applied to the stress, permitting examination of the Monin‐Obukhov formulation, no such correction procedure is possible with respect to γ ω S σ S and σ ω .
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A. B. Bernstein (1966) studied this question.
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