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January 1, 1978Journal of the Chemical Society Chemical Communications290 citations

An unusually stable thionitrite from N-acetyl-D,L-penicillamine; X-ray crystal and molecular structure of 2-(acetylamino)-2-carboxy-1,1-dimethylethyl thionitrite

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LFLamar FieldRDRobert V. DiltsRRR. Ravichandran

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Abstract

N-Acetyl-D,L-penicillamine (1) was converted by HNO2 into a thionitrite (3) which was stable as a solid and atypically so even in solution; X-ray structural parameters are given for (3), and both homolytic and heterolytic reactions are described.

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Cite This Study

Field et al. (1978) studied this question.

synapsesocial.com/papers/6a28c0da19023cdc0222dc55https://doi.org/10.1039/c39780000249
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