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June 13, 2026Angewandte Chemie International Edition

From P‐Type to Bipolar: A Quinone‐Core Engineering Strategy in D‐A‐D Organic Cathodes for Ultra‐Stable and High‐Energy Organic Lithium‐Ion Batteries

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Authors

XWXinyu WangXCXiangxu ChengGZGuoqing Zhao

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Overview

Randomized trial demonstrates high energy and stability in organic lithium-ion battery cathodes, suggesting advanced material design benefits.

Key Points

  • This study aims to develop high-performance organic cathodes using a donor-acceptor-donor molecular design to enhance charge transfer efficiency.
  • Designed and synthesized two organic molecules: PTZBQ with a quinone core and PTZTAB without a quinone core.
  • Evaluated the electronic structure, electrode kinetics, and charge transfer characteristics through DFT calculations and spectroscopy.
  • Tested the materials' discharge potential, specific capacity, and cycling stability under various conditions.
  • PTZBQ exhibits a discharge potential of 3.05 V and a specific capacity of 163.3 mAh g -1 at 0.1 A g -1 .
  • Demonstrated 77.6% capacity retention at 5 A g -1 and 89.4% retention after 5000 cycles at 1 A g -1 .
  • Enhanced interfacial charge transfer leads to improved electrode performance and stability.

Cite This Study

Wang et al. (2026) studied this question.

synapsesocial.com/papers/6a2cf4aefaef96ed7f056eb7https://doi.org/10.1002/anie.9678457
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