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Demonstrates site-selective glycoside formation in sugars, suggesting new therapeutic applications.
Herein, we describe a photoinduced Ni-catalyzed protocol that leverages the potential of cyclic acetals as vehicles for accessing glycosides bearing carbon-carbon linkages distal to the anomeric position. This method offers a new gateway to elusive compounds with high site selectivity, providing new opportunities in sugar-based therapeutics with lipophilic side chains.
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Zhang et al. (2026) studied this question.
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