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ABSTRACT Contrary to the conventional belief that humic coal generates primarily gas, 3 billion bbl of recoverable oil has been discovered in the humic coaly succession of the fluviodeltaic Latrobe Group (Upper Cretaceous-Tertiary) that serves as both the reservoir and the source for hydrocarbons in the offshore Gippsland basin of southeastern Australia. Evidence for generation of liquid hydrocarbons from the coaly succession includes: (1) similarity of n-alkane distribution in the oil and in the coal extracts; (2) high wax content of oil (up to 27% by weight); (3) high ratio of pristane/phytane in oil (5-6); and (4) dominance of C29 steranes in the oil. In the Gippsland basin, coniferous rain forests dominated by kauri vegetation flourished in a raised bog setting. Present temperate climate and kauri vegetation of New Zealand are considered to be the modern analog to the Gippsland basin. The coniferous vegetation provided large quantities of hydrogen-rich exinite macerals, such as cutinite and resinite, with potential to generate oil. High rainfall, raised ground-water level, low oxygen, high acidity, and low-nutrient conditions of a raised bog setting were suitable for preserving organic matter. A comparison of gas chromatograms of oils in the Gippsland basin with gas chromatograms of oils generated by hydrous pyrolysis in the laboratory from the immature source rocks suggests that the paraffinic fraction of the oil was derived from coal, and the naphthenic fraction was derived chiefly from resin.
G. Shanmugam (Thu,) studied this question.