Utility of a Rh(III) embedded covalent organic polymer as an efficient photocatalyst for visible-light driven N-formylation of amines and CO2 reduction under green and sustainable condition

Rhitama Mandal; Amitesh Roy; Titu Mondal; Priyanka Sarkar; Subhas Chandra Debnath; Swarbhanu Ghosh; Aslam Khan; Sk Manirul Islam

doi:10.1039/d6cy00348f

January 1, 2026Catalysis Science & Technology

Utility of a Rh(III) embedded covalent organic polymer as an efficient photocatalyst for visible-light driven N-formylation of amines and CO2 reduction under green and sustainable condition

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Key Points

The aim is to evaluate the efficiency of a Rh(III) embedded covalent organic polymer as a photocatalyst.
Synthesis of an imidazole-linked covalent organic polymer using 2,4,6-triformylphluroglucinol and 3,3`-diaminobenzidine.
Rhodium (Rh(III)) was incorporated to enhance photocatalytic activity.
Photocatalytic activities were tested under visible light in green and sustainable conditions.
Rh(III) embedded COP showed significantly increased photocatalytic efficiency.
The product yield for N-formylation of amines was markedly improved, demonstrating effective CO2 reduction.
Sustainable conditions facilitated the success of the photocatalytic reactions.

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Implication

Demonstrates efficient N-formylation and CO2 reduction in sustainable conditions, indicating potential for green chemistry.

Abstract

An imidazole-linked covalent organic polymer (COP) was synthesized with the combination of 2,4,6-triformylphluroglucinol and 3,3`-diaminobenzidine, TPDB. To enhance the photocatalytic activity of the synthesized COF, Rhodium was grafted as Rh(III)...

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Mandal et al. (2026) studied this question.

synapsesocial.com/papers/6a2e4753b1cc60ccdea8bcff https://doi.org/10.1039/d6cy00348f

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Utility of a Rh(III) embedded covalent organic polymer as an efficient photocatalyst for visible-light driven N-formylation of amines and CO2 reduction under green and sustainable condition

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Implication

Abstract

Discussion

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Utility of a Rh(III) embedded covalent organic polymer as an efficient photocatalyst for visible-light driven N-formylation of amines and CO2 reduction under green and sustainable condition

Key Points

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Abstract

Discussion

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