Efficient electrogenerated chemiluminescences (ECLs) of three pyrrolopyrrole aza-BODIPYs in the near-infrared region by using tripropylamine as a coreactant are reported. Kinetic analysis based on Marcus theory indicates the direct formation of S2 and T2 states through the electron transfer reaction, which affects the ECL efficiencies.
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Ishimatsu et al. (2019) studied this question.
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