Binder‐Free Electrodes for Advanced Sodium‐Ion Batteries

Sodium-ion batteries (SIBs) have recently emerged as one of the favored contenders for use in medium and large-scale stationary energy storage owing to the abundance of the resources required to fabricate them, their low cost, and the fact that have properties similar to equivalent Li batteries. However, their development also faces challenges such as poor cycling stability and unsatisfying rate performance. In traditional electrodes, binders are commonly used to integrate individual active materials with conductive additives. Unfortunately, binders are generally electrochemically inactive and insulating, which reduces the overall energy density and leads to poor cycling stability. Therefore, binder-free electrodes provide great opportunity for high-performance SIBs in terms of both improved electronic conductivity and electrochemical reaction reversibility. This Progress Report provides an overview of the recent progress in binder-free electrodes for SIBs. It focuses on the current challenges of binder-free electrodes and provides an outlook for their future in energy conversion and storage.