The direct assembly of four kinds of cages by face-sharing and edge-sharing modes with Zn 3 (μ 3 -OH – )(H 2 O)(COO – ) 4 units and organic ligands generates a porous framework material including 3D channels, which shows high adsorption enthalpy of C 3 H 8 (35 kJ/mol) and excellent adsorption selectivity of C 3 H 8 over CH 4 under ambient conditions.
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Wang et al. (2014) studied this question.
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