A molecular photosensitizer achieves a Voc of 1.24 V enabling highly efficient and stable dye-sensitized solar cells with copper(II/I)-based electrolyte

Abstract To develop photosensitizers with high open-circuit photovoltage ( V oc ) is a crucial strategy to enhance the power conversion efficiency (PCE) of co-sensitized solar cells. Here, we show a judiciously tailored organic photosensitizer, coded MS5, featuring the bulky donor N -(2’,4’-bis(dodecyloxy)-1,1’-biphenyl-4-yl)-2’,4’-bis(dodecyloxy)- N -phenyl-1,1’-biphenyl-4-amine and the electron acceptor 4-(benzo c 1,2,5thiadiazol-4-yl)benzoic acid. Employing MS5 with a copper (II/I) electrolyte enables a dye-sensitized solar cell (DSC) to achieve a strikingly high V oc of 1.24 V, with the V oc deficit as low as 130 mV and an ideality factor of merely 1.08. The co-sensitization of MS5 with the wider spectral-response dye XY1b produces a highly efficient and stable DSC with the PCE of 13.5% under standard AM1.5 G, 100 mW cm −2 solar radiation. Remarkably, the co-sensitized solar cell (active area of 2.8 cm 2 ) presents a record PCE of 34.5% under ambient light, rendering it very attractive as an ambient light harvesting energy source for low power electronics.