A Fe(II)-based metal-organic framework (MOF), {[Fe2(pbt)2(H2O)2]·2H2O}n, undergoes an irreversible dehydration, which triggers changes in the catalytic and magnetic properties of the MOF. These property changes are attributed to the high-spin to low-spin transition of 7.1% center Fe(II), which is demonstrated by (57)Fe Mössbauer, X-ray photoelectron spectroscopy, and UV/vis absorption spectra.
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Xu et al. (2014) studied this question.
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