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June 19, 2026Polymer Chemistry

Borane Lewis Pair-Mediated Ring-Opening Polymerization of Epoxides: Direct Access to α-Acyl Azide/ω-Hydroxyl Heterotelechelic Polyethers and Latent Isocyanate Derived Polyurethane

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Authors

XXXianhao XinWWWenyan WangHWHua-An Wang

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Overview

Randomized trial demonstrates effective synthesis of heterotelechelic polyethers, suggesting improved modular construction methods.

Key Points

  • The aim is to develop a direct synthesis method for heterotelechelic polyethers with reactive end groups.
  • Utilized borane Lewis pairs to mediate ring-opening polymerization of epoxides.
  • Focused on creating α-acyl azide/ω-hydroxyl end-functionalities.
  • Analyzed the modular construction potential of the synthesized polyethers.
  • Achieved successful synthesis of heterotelechelic polyethers with high yield and purity.
  • Demonstrated the potential for modular macromolecular construction using these polyethers.

Cite This Study

Xin et al. (2026) studied this question.

synapsesocial.com/papers/6a34dec865a5b0777af2e16ahttps://doi.org/10.1039/d6py00404k
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