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August 5, 2011The Journal of Organic Chemistry155 citations

Palladium-Catalyzed Synthesis of Dibenzophosphole Oxides via Intramolecular Dehydrogenative Cyclization

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YKYoichiro KuninobuTYTakuya YoshidaKTKazuhiko Takai

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Abstract

Dibenzophosphole oxides were obtained from secondary hydrophosphine oxides with a biphenyl group by dehydrogenation via phosphine-hydrogen and carbon-hydrogen bond cleavage in the presence of a catalytic amount of palladium(II) acetate, Pd(OAc)(2). By using this reaction, a ladder-type dibenzophosphole oxide could also be synthesized by double intramolecular dehydrogenative cyclization.

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Kuninobu et al. (2011) studied this question.

synapsesocial.com/papers/6a350de1375acbabf4ff9385https://doi.org/10.1021/jo201030j
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