Synthesizes diphenyl ethyne-bridged porphyrin dyads, highlighting new compound formation in organic chemistry.
The diphenyl ethyne-bridged 22-oxabenzonorrole–Zn( ii ) porphyrin dyad was synthesized via Pd(0)-catalyzed coupling. TFA demetallation followed by Cu( ii ) metalation afforded the corresponding Cu( ii ) dyad.
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Kabi et al. (2026) studied this question.
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