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June 20, 2026Accounts of Materials Research

Toward Autonomous Electrochemical Sensing: Advances and Challenges in Calibration-Free and Long-Duration Technologies

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Authors

LJLe JingQLQianqian LiSLS Y Li

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Overview

This Account demonstrates calibration-free sensing technologies for molecular monitoring in clinical settings, indicating promising advancements in biosensing accuracy and longevity.

Key Points

  • This research addresses the limitations of traditional electrochemical biosensors that require external calibration, aiming to enhance their long-term performance in complex biofluids.
  • Describes intrinsic dual-signal encoding strategy using two redox-reporters for ratiometric outputs.
  • Explains operationally programmed self-referencing strategy to extract drift-differentiated kinetics.
  • Discusses interfacial engineering to reduce signal decay through optimization of molecular components.
  • The dual-signal strategy produces self-normalized readouts without the need for calibration.
  • Self-referencing strategy effectively compensates for signal drift in fluctuating environments.
  • Interfacial engineering demonstrates improved longevity of electrochemical signals in complex settings.

Cite This Study

Jing et al. (2026) studied this question.

synapsesocial.com/papers/6a362f92db0793dc1a536fa3https://doi.org/10.1021/accountsmr.6c00038
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