Pillared MXene with Ultralarge Interlayer Spacing as a Stable Matrix for High Performance Sodium Metal Anodes

Abstract Sodium (Na) metal is a promising alternative to lithium metal as an anode material for the next‐generation energy storage systems due to its high theoretical capacity, low cost, and natural abundance. However, dendritic/mossy Na growth caused by uncontrollable plating/stripping results in serious safe concerns and rapid electrode degradation. This study presents Sn 2+ pillared Ti 3 C 2 MXene serving as a stable matrix for high‐performance dendrite‐free Na metal anode. The intercalated Sn 2+ between Ti 3 C 2 layers not only induces Na to nucleate and grow within Ti 3 C 2 interlayers, but also endows the Ti 3 C 2 with larger interlayer space to accommodate the deposited Na by taking advantage of the “pillar effect,” contributing to uniform Na deposition. As a result, the pillar‐structured MXene‐based Na metal electrode could enable high current density (up to 10 mA cm −2 ) along with high areal capacity (up to 5 mAh cm −2 ) over long‐term cycling (up to 500 cycles). The full cell using MXene‐based Na metal anode exhibits superior electrochemical performance than that using host‐less commercial Na. It is believed that the well‐controlled MXene‐based Na anode not only extends the application scope of MXene, but also provides guidance in designing high‐performance Na metal batteries.