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Investigates changes in liquid-liquid transitions in ionic liquids, suggesting intrinsic properties of ether bonds.
][TFSI], the polar/nonpolar nanodomains were not formed due to the flexible and curled alkyl chains. Despite no nanodomain, HP LLT occurred with changing the local structures. A series of quaternary ammonium and phosphonium ILs exhibited entirely different HP behavior, which implies that the ether bonds of the cations have an intrinsic property.
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Abe et al. (2026) studied this question.
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