ABSTRACT Modern high‐electron‐mobility transistors (HEMTs) and light‐emitting diodes (LEDs) are engineered around epitaxial indium gallium nitride (In x Ga 1 − x N) heterostructures. We apply the highest‐resolution structural, elemental, and optical characterization to a series of systematically fabricated GaN‐on‐silicon (Si) epitaxial heterostructures and demonstrate hitherto unresolved nanoscale optical inhomogeneities in individual In x Ga 1 − x N quantum wells. Direct correlation of atom probe tomography and scanning transmission electron microscopy with cathodoluminescence collectively confirms that these optical inhomogeneities result from compositional segregation that only appears in high indium‐content In x Ga 1−x N specimens, but not in low indium‐content quantum wells, thereby elucidating the origin of injection‐current‐induced blueshifts in long wavelength LEDs. Density functional theory (DFT) calculations of the various alloy mixing energies indicate that the relaxation of the epitaxial in‐plane strain stabilizes specific In x Ga 1−x N compositions. Our findings suggest that proper use of strain management and careful selection of alloy compositions are necessary to control local phase separation. This work presents a path to high‐mobility strain engineering in HEMTs and homogeneous, long‐wavelength light emission in LEDs.
Chung et al. (Mon,) studied this question.