Spaceborne imaging spectroscopy has created new opportunities for monitoring soil properties at regional scales. Its use for predicting soil heavy metal concentrations in mountainous environments, however, remains insufficiently tested, especially when EMIT hyperspectral data are used. In this study, EMIT Level-2A surface reflectance data were integrated with DEM-derived terrain variables to estimate soil arsenic (As), copper (Cu), and zinc (Zn) concentrations in Renhuai, Guizhou Province, Southwest China. Only soil samples falling within valid EMIT coverage were used for element-specific modeling, resulting in 139 samples for As, 136 for Cu, and 130 for Zn. To reduce redundancy among predictors, EMIT spectral variables and terrain factors were screened before model construction. Random forest and XGBoost models were then tested using repeated spatial cross-validation. The best-performing model for As combined EMIT predictors with elevation and achieved a validation R2 of 0.460. Model performance was considerably weaker for Cu, with a validation R2 of 0.188. For Zn, the model failed to outperform the mean-based benchmark, producing a negative validation R2 of −0.028. The spatial prediction maps and residual patterns suggested that the EMIT-based prediction showed moderate potential for As, limited predictive value for Cu, and exploratory rather than reliable mapping capability for Zn under the current sample and predictor conditions.
Qie et al. (Sun,) studied this question.
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