Research reveals how nucleobase topology affects low-valent Rh and Ir architectures, suggesting new design principles for metal-organic assemblies.
framework forms a closed metal-organic polyhedron with a gyrobifastigium topology reinforced by a continuous N-H···O hydrogen-bond belt. These results highlight how differences in nucleobase donor topology and hydrogen-bonding capability influence the assembly of low-valent Rh(I) and Ir(I) architectures.
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Badía et al. (2026) studied this question.
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