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July 11, 2026The Journal of Chemical PhysicsOpen Access

Reimagining singlet exciton fission: Insights from dimer architectures

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Authors

AMAisworika MohantyAKArup KunduJDJyotishman Dasgupta

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Overview

Perspective discusses mechanistic insights of singlet fission in dimeric systems, suggesting strategies for effective triplet extraction.

Key Points

  • This perspective aims to provide a detailed understanding of singlet fission mechanisms and the role of dimer architectures in optimizing triplet extraction.
  • Summarized findings from time-resolved and steady-state spectroscopic investigations on dimeric chromophore systems.
  • Reviewed relaxation and loss pathways following triplet-triplet pair formation.
  • Discussed strategies for enhancing triplet exciton dissociation from dimer structures.
  • Identified key pathways that reduce effective triplet yield to below 100%.
  • Outlined methods for promoting dissociation of triplet-triplet pairs into free triplets.
  • Presented strategies for more efficient triplet extraction from dimer architectures.

Cite This Study

Mohanty et al. (2026) studied this question.

synapsesocial.com/papers/6a51df9fc18d7f28ca500a28https://doi.org/10.1063/5.0333488
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