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A stable Cu(0)-containing nanocluster, [Cu23H4(SC7H7)18(PPh3)6], can be synthesized by protecting the highly reactive Cu(0) center with Cu(I)-based Johnson solids, resulting in exceptional structural stability and selective electrocatalytic reduction of CO2 to HCOOH. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

Atomically Precise Cu 23 H 4 (SC 7 H 7 ) 18 (PPh 3 ) 6 Nanocluster: Structural Integration of Johnson Solids through a Cu(0) Center and Electrocatalytic Functionality

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