Synthesis and characterisation of highly branched polyisoprene: exploiting the “Strathclyde route” in anionic polymerisation

H NMR spectroscopy reveals the dominance of 3,4-polyisoprene microstructure. It was found that the complex viscosities and dynamic moduli of the branched samples were much lower compared to their linear counterparts. The results conform with earlier findings by the "Strathclyde team" for radical polymerisation systems. This methodology has the potential of providing soluble branched vinyl polymers at low cost using the readily available raw materials.