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Investigates manganese-catalyzed silylation of alkenes, suggesting efficient reaction pathways.
-vinylsilanes and allylsilanes, respectively, at room temperature. Mechanistic insights are provided based on experimental data and DFT calculations revealing that two parallel reaction pathways are operative: an acceptorless reaction pathway involving dihydrogen release and a pathway requiring an alkene as sacrificial hydrogen acceptor.
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Weber et al. (2021) studied this question.
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