Alignment properties of a ferroelectric nematic liquid crystal on the rubbed substrates

The orientation characteristics of FNLC-919, a new material with a ferroelectric nematic phase at room temperature, were investigated. Its alignment characteristics varied greatly depending on the relative rubbing direction on both substrates of a liquid crystal cell. In a cell where the two substrates were rubbed in the same direction, they were arranged homogeneously along the rubbing direction without domains or defects in the ferroelectric nematic phase. In a cell where the two substrates were rubbed in the anti-parallel direction, the two domains were twisted in the opposite direction. We quantitatively obtained the twisted direction and angle by matching the experimental data and calculation results using Jones matrix calculations. From the electro-optical experiment, it was confirmed that the polarization direction was opposite to the rubbing direction. In addition, the wavelength and temperature dependence of birefringence was measured for FNLC-919. In a cell where the rubbing direction between two substrates was 90°, two domains of opposite directions were observed in the nematic phase. When it becomes a ferroelectric nematic phase on cooling, the twist is determined to be only in one direction. The twist direction and angle were quantitatively obtained in the nematic and ferroelectric nematic phases. It was twisted more in the ferroelectric nematic phase than in the nematic phase.