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July 17, 2026Journal of the American Chemical Society

Scope of Ni(II)-Catalyzed Nonalternating Ethylene/Carbon Monoxide Copolymerization

Lukas Wursthorn Steffen Iberl Yajun Zhao Michele Tomasini Marie Fritschi Ida Ritacco Maria Voccia Laura Falivene Kohei Takahashi Bin Lu Kyoko Nozaki Lucia Caporaso Stefan Mecking

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Key Points

The study aims to explore how NHC ligands affect the copolymerization of ethylene and carbon monoxide.
Investigated the influence of NHC,O-ligand on the copolymerization process.
Analyzed the steric hindrance effects on CO incorporation during the reaction.
Demonstrated an exceptionally low preference for CO incorporation due to steric hindrance.
Found that the choice of ligand significantly impacts polymer composition.

Implication

Research reveals the impact of NHC ligands on CO incorporation in copolymerization using Ni(II) catalysts.

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Cite This Study

Wursthorn et al. (2026) studied this question.

synapsesocial.com/papers/6a5dba128bd453d3397ab50d https://doi.org/10.1021/jacs.6c07158

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Attractive Ni <sup>…</sup> O Interactions Enable Non‐Alternating Ethylene‐Carbon Monoxide CopolymerizationOriginal Research · 2026 · 2 citations
2Attractive Ni <sup>…</sup> O Interactions Enable Non‐Alternating Ethylene‐Carbon Monoxide CopolymerizationOriginal Research · 2026
3Effect of Interactions Between the Ligand Distal Group and Cocatalyst in Nickel(<scp>II</scp>)‐Catalyzed Ethylene Polymerization2025
4Macrocyclic-Constrained Bulky Binuclear Nickel Catalyst for Ethylene (Co)PolymerizationOriginal Research · 2026 · 1 citations
5Favorable Propylene-Incorporated Terpolymerization of Ethylene with CO Mediated by Cationic [P,O]-Pd and Ni ComplexesOriginal Research · 2023 · 13 citations

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