February 13, 2014Chemistry - A European Journal174 citations

Carbene‐9‐BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO2 Reduction

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Abstract

Reactions of phosphine-derived carbenes with 9-borabicyclo3.3.1nonane (9-BBN) result in ring-expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs). These FLPs effect the catalytic reduction of CO2 in the presence of boranes to give BOB and methoxy-borate species.

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Wang et al. (Thu,) studied this question.

synapsesocial.com/papers/6a5e141d69f6c368eabc457d https://doi.org/https://doi.org/10.1002/chem.201304870

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5Catalytic Reduction of CO2 to CO by Using Zinc(II) and In Situ Generated Carbodiphosphoranes2013 · 48 citations

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