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June 1, 2009Journal of the American Chemical Society435 citations

Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs

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MDM.A. DureenDSDouglas W. Stephan

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Abstract

Frustrated and classical Lewis pairs arising from combinations of Lewis acids and phosphines react with terminal alkynes either via C-H activation forming an alkynylborate salt or by addition to alkyne giving a zwitterionic phosphonium borate.

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Cite This Study

Dureen et al. (2009) studied this question.

synapsesocial.com/papers/6a5e141d69f6c368eabc458ehttps://doi.org/10.1021/ja903650w
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