Enhancing Built-in Electric Field via Molecular Dipole Control in Conjugated Microporous Polymers for Boosting Charge Separation

-mediated coupling of bicarbazole with different acceptor cores. The optimized CbzCMP-9 featured the strongest BEF induced by its high molecular dipole, which grants it with a powerful driving force to accelerate exciton dissociation into electron-hole pairs and facilitates charge transfer along the backbone of CMPs to the surface, resulting in a remarkable photocatalytic performance toward thiocyano chromones and C-3 thiocyanation of indoles (up to 95 and 98% yields, respectively) and prominently surpassing many other reported photocatalysts. In brief, the proposed strategy highlights that enhancing the BEF by modulating molecular dipole can lead to a dramatic improvement in photocatalytic performance, which is expected to be employed for constructing other photocatalytic systems with high performance.