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January 7, 2011Angewandte Chemie International Edition183 citations

Photon‐Quantitative Reaction of a Dithiazolylarylene in Solution

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SFSayo FukumotoTNTakuya NakashimaTKTsuyoshi Kawai

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Abstract

Ready for action: An excellent quantum yield was observed for a photocoloration reaction of a photochromic molecule based on a triangular terarylene structure. The molecule is brought into a conformation favorable for photocyclization by multiple intramolecular interactions, including CHN hydrogen bonding and SN and CHπ interactions (see picture).

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Fukumoto et al. (2011) studied this question.

synapsesocial.com/papers/6a5e1f6771fb0cfecebc3d5chttps://doi.org/10.1002/anie.201006844
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