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August 6, 2004Chemical Reviews

Synthesis and Reactivity of Ru-, Os-, Rh-, and Ir-Halide−Sulfoxide Complexes

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Abstract

This article, based on the author's first hand experience, makes a thorough and detailed account of the chemistry of widely used precursors in inorganic synthesis, i.e. ruthenium(III/II), osmium(II), rhodium(III/I), and iridium(III/I)-halide-sulfoxide complexes

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Cite This Study

Enzo Alessio (2004) studied this question.

synapsesocial.com/papers/6a5e3cf905d8882f8537d7fb https://doi.org/10.1021/cr0307291

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Crystal and molecular structure of dichlorotetrakis(dimethyl sulphoxide)ruthenium(II)Original Research · 1975 · 61 citations
2Ruthenium (II) complexes of 4-nitroimidazoles: their characterization, solution chemistry, and radiosensitizing activityOriginal Research · 1988 · 47 citations
3Effects of halide (X) and sulfoxide (R<sub>2</sub>SO) replacement within the ruthenium(II) nitroimidazole complexes, RuX<sub>2</sub>(R<sub>2</sub>SO)<sub><i>m</i></sub>, (nitroimidazole)<sub><i>n</i></sub>, <i>m</i> = 1-3, <i>n</i> = 1 or 2: their characterization, solution chemistry, radiosensitizing activity, and related propertiesOriginal Research · 1989 · 44 citations
4Mechanistic studies of the selective oxygen oxidation of sulfides to sulfoxides catalyzed by dihaloruthenium(II) complexesOriginal Research · 1984 · 70 citations
5Isolation and Characterization of a Dimeric Ruthenium(II) Complex. An Intermediate in the Ruthenium-Catalyzed Oxygen Oxidation of Thioethers to SulfoxidesOriginal Research · 1988 · 6 citations

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Selective oxidation of thioethers to sulfoxides with molecular oxygen mediated by rhodium(III)–dimethylsulfoxide complexes2001
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