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Abstract Simple functions do not adequately describe the hydraulic properties of many field soils, particularly those with substantial macroporosity. By considering the soil pore‐size distribution f (ψ) = Σ N i = 1 ψ i f i (ψ) corresponding to the effective saturation S (ψ) = Σ N i = 1 ψ i S i (ψ), where ψ is matric pressure head, the ψ i are fractions of effective porosity, the S i (ψ) are simple water retention functions in common use, and f i (ψ) = S ' i (ψ), we show that the relative hydraulic conductivity according to the Mualem model is K r (ψ) = S p ΣΣ N i = 1 ψ i g i (ψ)/Σ N i = 1 ψ i g i (0) 2 , where g i (ψ) = ε ψ ‐x ψ −1 f i (ψ) dψ and p is a pore interaction index. If the pores of the distributions do not interact, the appropriate relation is K (ψ) = Σ N i = 1 K si K ri (ψ), where K si is the saturated conductivity of distribution i and K ri = S p g i (ψ)/ g i (0) 2 . We note that the van Genuchten function S (ψ) = 1 + (−αψ) n − m with the restriction m = 1 − 1/ n leads to an infinite slope K '(ψ) at ψ = 0 unless n ≥ 2, which is unrealistic for field soils if a wide range of matric pressure heads is considered. Hydraulic conductivity near saturation is often expressed as K (ψ) = K s exp( a ψ). We introduce the function S (ψ) = (1 − αψ) exp(αψ), which gives, according to Mualem's model, a conductivity K (ψ) = K s (1 − αψ) p exp( p + 2)αψ that approximates K s exp(αψ) near saturation if a = 2α and is exactly equal if p = 0. As an example, a function using this model for one pore‐size distribution and the van Genuchten model for the other was compared with a function using two van Genuchten distributions. The latter gave a slightly improved fit to water content and conductivity data for an aggregated soil.
Ross et al. (Fri,) studied this question.