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Polymer networks have gained great attention due to their unique structural arrangement and characteristic properties. The interconnection of polymer chains can be achieved through covalent or noncovalent interactions. However, it remains a challenge to explore a strategy for the precise integration of covalent and noncovalent cross-linking within polymer network architectures. In this work, we designed and synthesized hydrogen-bonding preorganized arylhydrazone dual-arm monomer 1 ( M1 ) and triarm monomer 2 ( M2 ), which were used to fabricate covalent polymer networks ( CPN s), CPN1 and CPN2, via acid-catalyzed macrocyclization. The resulting CPN1 and CPN2 exhibited well-defined electron-rich macrocyclic cavities, enabling subsequent supramolecular cross-linking with bipyridinium guest ( BP ) to generate supramolecular/covalent polymer networks ( SCPN s), SCPN1 and SCPN2 . CPN1 formed denser, more flexible films compared to the brittle CPN2, highlighting the importance of appropriate covalent cross-linking density. Importantly, incorporation of BP significantly improved the mechanical properties of the networks, including Young’s modulus, tensile strength, and toughness, demonstrating the effectiveness of host–guest interactions in reinforcing polymer network structures and the potential of macrocycle-driven supramolecular engineering for advanced material design.
Li et al. (Mon,) studied this question.