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A theoretical investigation of extremely high field transport in an emerging wide-bandgap material β-Ga2O3 is reported from first principles. The signature high-field effect explored here is impact ionization. The interaction between a valence-band electron and an excited electron is computed from the matrix elements of a screened Coulomb operator. Maximally localized Wannier functions are utilized in computing the impact ionization rates. A full-band Monte Carlo simulation is carried out incorporating the impact ionization rates and electron-phonon scattering rates. This work brings out valuable insights into the impact ionization coefficient (IIC) of electrons in β-Ga2O3. The isolation of the Γ point conduction band minimum by a significantly high energy from other satellite band pockets plays a vital role in determining ionization co-efficients. IICs are calculated for electric fields ranging up to 8 MV/cm for different crystal directions. A Chynoweth fitting of the computed IICs is done to calibrate ionization models in device simulators.
Ghosh et al. (Tue,) studied this question.
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