Key points are not available for this paper at this time.
Abstract ( k 0 / k ∞)‐reduced strong collision fall‐off curves of thermal unimolecular reactions are analyzed. They are represented by the Lindemann‐Hinshelwood expression multiplied by strong collision broadening factors F SC . The factors F SC are approximated by fully empirical representations of RRKM theory. Compact expressions suitable for modeling are proposed. Their quality is demonstrated by comparison with exact RRKM calculations for 20 molecular systems.
J. Troe (Tue,) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: