Thermal stabilization of energetic materials by the aromatic nitrogen-rich 4,4′,5,5′-tetraamino-3,3′-bi-1,2,4-triazolium cation

Crystals of the highly energetic material 4,4′,5,5′-tetraamino-3,3′-bi-1,2,4-triazolium dinitramide ( 2 ). This compound is representative for the improvement of thermal stability resulting from the insertion of the long disregarded 4,4′,5,5′-tetraamino-3,3′-bi-1,2,4-triazolium cation.