Ultrafast Sodium/Potassium‐Ion Intercalation into Hierarchically Porous Thin Carbon Shells

Abstract The large‐scale application of sodium/potassium‐ion batteries is severely limited by the low and slow charge storage dynamics of electrode materials. The crystalline carbons exhibit poor insertion capability of large Na + /K + ions, which limits the storage capability of Na/K batteries. Herein, porous S and N co‐doped thin carbon (S/N@C) with shell‐like (shell size ≈20–30 nm, shell wall ≈8–10 nm) morphology for enhanced Na + /K + storage is presented. Thanks to the hollow structure and thin shell‐wall, S/N@C exhibits an excellent Na + /K + storage capability with fast mass transport at higher current densities, leading to limited compromise over charge storage at high charge/discharge rates. The S/N@C delivers a high reversible capacity of 448 mAh g ‐1 for Na battery, at the current density of 100 mA g ‐1 and maintains a discharge capacity up to 337 mAh g ‐1 at 1000 mA g ‐1 . Owing to shortened diffusion pathways, S/N@C delivers an unprecedented discharge capacity of 204 and 169 mAh g ‐1 at extremely high current densities of 16 000 and 32 000 mA g ‐1 , respectively, with excellent reversible capacity for 4500 cycles. Moreover, S/N@C exhibits high K + storage capability (320 mAh g ‐1 at current density of 50 mA g ‐1 ) and excellent cyclic life.