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Herein, we report an anthracene-based material, 2-(anthracen-9-yl)thianthrene (), whose crystal exhibits excimer fluorescence with an unexpected high luminous efficiency (up to 80%) and long lifetime (163.75 ns), due to pairwise anthracene stacking. These results will update the traditional view that excimers are poorly efficient in photoluminescence.
Liu et al. (Fri,) studied this question.