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A phenothiazine derivative of FCO-CzS with changeable mechanoluminescence is reported, which, upon continuous mechanical stimulus, shows mechanoluminescent emission from blue to white and yellow. Careful analysis of the experimental results, coupled with the well-understood photoluminescence theory, show that the molecular conformation transition of the phenothiazine group from quasi-axial to quasi-equatorial is responsible for this dynamic mechanoluminescence effect.
Yang et al. (Wed,) studied this question.