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Examines inner and meso functionalizations of porphyrin derivatives using ethanol.
Conjugate addition of ethanol and subsequent oxidation with [bis (trifluoroacetoxy)iodo]benzene (PIFA) allowed for the inner ethoxylation of 3‐oxo‐N‐confused tetraphenylporphyrin ( ONCP ). First oxidation of ONCP with PIFA followed by treatment with ethanol gave two more N‐confused phlorins derivatives 5 and 6 .
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Zhang et al. (2023) studied this question.
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