Structure‐Driven Orientation of the High‐Spin–Low‐Spin Interface in a Spin‐Crossover Single Crystal

The orientation of the high-spin (HS)-low-spin (LS) macroscopic interface at the thermal transition of thin [{Fe(NCSe)(py)2}2(m-bpypz)] crystals is explained by considering the possible vanishing of the structural mismatch between the coexisting phases. The structural property which allows mismatch-free interfaces is characterized. The observed orientations of the interface and the tilt angle between the HS and LS domains are accurately reproduced by a two-dimensional continuous medium model, based on the structural data. Simulations using an atomistic electro-elastic model meet the predictions of the macroscopic analysis and provide information on the distribution of the elastic energy density in the biphasic state. The presence of mismatch-free domain structures can explain the exceptional resilience of these crystals upon repeated switching.